This attack aims to use the user NTLM hash to request Kerberos tickets, as an alternative to the common Pass The Hash over NTLM protocol. Therefore, this could be especially useful in networks where NTLM protocol is disabled and only Kerberos is allowed as authentication protocol.
In order to perform this attack, the NTLM hash (or password) of the target user account is needed. Thus, once a user hash is obtained, a TGT can be requested for that account. Finally, it is possible to access any service or machine where the user account has permissions.
This kind of attack is similar to Pass the Key, but instead of using hashes to request for a ticket, the ticket itself is stolen and used to authenticate as its owner.